中國有色金屬學報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 32 No. 10 October 2022 |
（1. State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China;
2. Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China;
3. School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China;
4. College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China;
5. College of Materials and Chemical Engineering, Tongren University, Tongren 554300, China）
Abstract:A novel adsorbent (MTZ-MOFs) was synthesized by a one-step reaction of zinc nitrate hexahydrate and 1-(2-dimethylaminoethyl)-1H-5-mercaptotetrazole to remove mercury from waste water. The results showed that MTZ-MOFs had excellent selectivity and repeatability for Hg(II), the optimum pH was 3.0, the maximum adsorption capacity was 872.8 mg/g, and the process was a spontaneous exothermic reaction. The adsorption behavior was chemisorption, which conformed to the pseudo-second-order kinetic and Freundlich isothermal model. Moreover, the adsorption mechanism showed that the adsorption process mainly depended on ion exchange and chelation, and the synergistic action of S and N atoms played a key role. So, MTZ-MOFs were an efficient adsorbent for mercury ion removal.
Key words: metal organic frameworks (MOFs); Hg(II); adsorption; selectivity; mechanism
