中國有色金屬學(xué)報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 32 No. 2 February 2022 |
（1. Hunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha 410114, China;
2. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,Changsha University of Science and Technology, Changsha 410114, China;
3. College of Materials Science and Engineering, Hunan University, Changsha 410082, China）
Abstract:The Ni-25%X (X=Fe, Co, Cu, molar fraction) solid solutions were prepared and then doped into MgH2 through high-energy ball milling. The initial dehydrogenation temperatures of MgH2/Ni-25%X composites are all decreased by about 90 °C relative to the as-milled pristine MgH2. The Ni-25%Co solid solution exhibits the most excellent catalytic effect, and the milled MgH2/Ni-25%Co composite can release 5.19 wt.% hydrogen within 10 min at 300 °C, while the as-milled pristine MgH2 can only release 1.78 wt.% hydrogen.More importantly, the dehydrogenated MgH2/Ni-25%Co composite can absorb 5.39 wt.% hydrogen at 275 °C within 3 min. The superior hydrogen sorption kinetics of MgH2/Ni-25%Co can be ascribed to the actual catalytic effect of in-situ formed Mg2Ni(Co) compounds. First-principles calculations show that the hydrogen absorption/desorption energy barriers of Mg/MgH2 systems decrease significantly after doping with transition metal atoms, which interprets well the improved hydrogen sorption properties of MgH2 catalyzed by Ni-based solid solutions.
Key words: MgH2; Ni-based solid solutions; catalytic effect; hydrogen storage properties; first-principles calculations
