(1. 東北大學(xué) 冶金學(xué)院，沈陽(yáng)110819；
2. 東北大學(xué) 材料電磁過(guò)程研究教育部重點(diǎn)實(shí)驗(yàn)室，沈陽(yáng) 110819；
3. 東北大學(xué) 低碳鋼鐵前沿技術(shù)研究院，沈陽(yáng) 110819；
4. 東北大學(xué) 遼寧省低碳鋼鐵技術(shù)工程研究中心，沈陽(yáng) 110819)
摘 要: 近年來(lái)，隨著社會(huì)的發(fā)展，傳統(tǒng)化石能源消耗急劇增加，環(huán)境問(wèn)題日益加劇，可再生清潔能源的開發(fā)迫在眉睫。電化學(xué)水分解法是公認(rèn)為將電能轉(zhuǎn)化為氫燃料的一種實(shí)用策略。因此，為了實(shí)現(xiàn)大規(guī)模制氫，開發(fā)低成本、資源豐富、高效且穩(wěn)定的電催化劑至關(guān)重要。過(guò)渡金屬磷化物具有價(jià)格低廉、資源豐富、化學(xué)穩(wěn)定性等特點(diǎn)，被廣泛應(yīng)用于電催化析氫領(lǐng)域。本文總結(jié)了過(guò)渡金屬磷化物用于電催化析氫的制備方法，且詳細(xì)概述了從形貌設(shè)計(jì)、界面調(diào)控、材料復(fù)合3個(gè)方面，提高電解水析氫反應(yīng)性能，并對(duì)其今后發(fā)展趨勢(shì)以及面臨的機(jī)遇和挑戰(zhàn)進(jìn)行展望。
關(guān)鍵字: 過(guò)渡金屬磷化物；析氫反應(yīng)；形貌設(shè)計(jì)；界面調(diào)控；材料復(fù)合
（1. School of Metallurgy, Northeastern University, Shenyang 110819, China;
2. Key Laboratory of Material Electromagnetic Process Research Ministry of Education, Northeastern University, Shenyang 110819, China;
3. Institute for Frontier Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China
4. Liaoning Province Engineering Research Center for Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China）
Abstract:In recent years, with the development of society, the consumption of traditional fossil energy has increased dramatically, and the environmental problems have become increasingly serious. Electrochemical water decomposition is a practical strategy for converting electric energy into hydrogen fuel. Therefore, in order to achieve large-scale hydrogen production, it is very important to develop low-cost, resource rich, efficient and stable electrocatalysts. Transition metal phosphides are widely used in the field of electrocatalytic dilute hydrogen because of their low price, good conductivity and chemical stability. In this paper, the preparation methods of transition metal phosphides for electrocatalytic hydrogen evolution were summarized, and the improvement of hydrogen evolution performance of electrolyzed water from three aspects of morphology design, interface control and material composite were summarized in detail. The future development trend, opportunities and challenges are also prospected.
Key words: transition metal phosphide; hydrogen evolution reaction; morphology design; interface control; material composite
