Abstract:As-cast samples of the Al-3wt.%Ni-1wt.%Bi alloy resulting from the horizontal directional solidification process were subjected to the micro-abrasive wear test. The effects of the solidification thermal and microstructural parameters, such as the growth and cooling rates and the cellular and primary dendritic spacings (V_L and T_R; l₁ and l_c; respectively), were evaluated in the wear resistance of the investigated alloy. The tribological parameters analyzed were the wear volume and rate (V_w and R_w). The solidification experiments and the wear tests were carried out by means of a water-cooled horizontal directional solidification device and a rotary-fixed ball wear machine, respectively. The results show lower V_w and R_w values correspond to finer microstructures and the V_w dependence on l₁ is characterized by an experimental mathematical equation. A better distribution of Bi soft droplets and Al₃Ni hard intermetallic particles is observed within the finer interdendritic region and, in consequence, the better wear resistance is achieved in as-cast samples with dendritic morphology rather than cellular morphology. A transition of wear mechanism from adhesive to abrasive is observed.

Key words: unsteady-state horizontal solidification; dry sliding wear; cellular/dendrite arm spacing; microhardness; Bi particle; Al₃Ni particle