(1. 中國科學(xué)院 過程工程研究所,北京 100190;
2. 中國科學(xué)院大學(xué) 化學(xué)工程學(xué)院,北京 100049;
3. 攀鋼集團(tuán)有限公司,攀枝花 617067)
摘 要: 釩、鉻是我國稀缺戰(zhàn)略金屬資源,廣泛應(yīng)用于冶金、化工、顏料及航空航天等領(lǐng)域,與國民經(jīng)濟(jì)密切相關(guān)。釩、鉻在礦物中常伴生存在,由于二者物理化學(xué)性質(zhì)相近,釩、鉻分離難度大。在系統(tǒng)分析釩、鉻溶液性質(zhì)的基礎(chǔ)上,綜述了高釩、高鉻溶液兩種情況下釩鉻分離方法的研究進(jìn)展,對化學(xué)沉淀法、溶劑萃取法、結(jié)晶分離法、離子交換法以及吸附分離法進(jìn)行了總結(jié),并探討了釩鉻分離方法的發(fā)展趨勢。
關(guān)鍵字: 釩;鉻;分離;研究進(jìn)展
(1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;
3. Pangang Group Co., Ltd., Panzhihua, 617067, China)
Abstract:Vanadium and chromium are scarce and important strategic metals in China, which widely used in metallurgy, chemical industry, pigment, aerospace and other fields, and plays a key role in the national economy. Vanadium is often associated with chromium in minerals. It is difficult to separate vanadium and chromium because of their similar physical and chemical properties. Based on the systematic analysis of the properties of the solution containing vanadium and chromium, the research progress of vanadium and chromium separation methods was reviewed in the case of high vanadium and high chromium solutions. The main methods include chemical precipitation, solvent extraction, crystallization separation, ion exchange and adsorption separation were summarized, and the development trend of vanadium and chromium separation methods was also discussed.
Key words: vanadium; chromium; separation; research progress


