中國有色金屬學(xué)報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 25 No. 4 April 2015 |
（School of Metallurgy and Environment, Central South University, Changsha 410083, China）
Abstract:The carbon-coated monoclinic Li3V2(PO4)3 (LVP) cathode materials were successfully synthesized by liquid phase method using PEG as reducing agent and carbon source. The effects of relative molecular mass of PEG on the properties of Li3V2(PO4)3/C were evaluated by X-ray diffraction (XRD), scanning electron microscope (SEM) and electrochemical performance tests. The SEM images show that smaller size particles are obtained by adding larger and smaller PEGs. The electrochemical cycling of Li3V2(PO4)3/C prepared by both PEG200 and PEG20k has a high initial discharge capacity of 131.1 mA·h/g at 0.1C during 3.0-4.2 V, and delivers a reversible discharge capacity of 123.6 mA·h/g over 30 cycles, which is better than that of other samples. The improvement in electrochemical performance is caused by its improved lithium ion diffusion coefficient for the macroporous morphology, which is verified by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS).
Key words: lithium-ion battery; lithium vanadium phosphate; PEG; carbon-coating; liquid phase method
