Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 24    No. 6    June 2014

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Thermodynamics and kinetics of adsorption for heavy metal ions from aqueous solutions onto surface amino-bacterial cellulose
Min LU, Yue-ming ZHANG, Xiao-hui GUAN, Xiao-hui XU, Ting-ting GAO

School of Chemical Engineering, Northeast Dianli University, Jilin 132012, China

Abstract:Amino-bacterial cellulose (amino-BC) was prepared by chemical modification of bacterial cellulose(BC). The adsorption characteristics and mechanism of amino-BC were studied. The results show that adsorption data can be fitted well by Langmuir equation and the pseudo-second order kinetics, indicating that the adsorption of amino-BC would obey monolayer molecule adsorption and the main action was chemisorption.Meanwhile, the adsorption process was studied by the Elovich equation and the intra-particle diffusion model, indicating that the absorption characteristics of metal ions on amino-BC is controlled by both film diffusion and particle diffusion.The increase of reaction temperature will accelerate the adsorbing rate because of endothermic reaction.

 

Key words: surface amination; bacterial cellulose; adsorption thermodynamics; adsorption kinetics

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學技術協(xié)會 主辦:中國有色金屬學會 承辦:中南大學
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