中國有色金屬學(xué)報(bào)(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 24 No. 5 May 2014 |
（1. HEDPS, Center for Applied Physics and Technology, LTCS, Department of Materials Science and Engineering,
College of Engineering, Peking University, Beijing 100871, China;
2. Key Laboratory of Condition Monitoring and Control for Power Plant Equipment of Ministry of Education,
North China Electric Power University, Beijing 102206, China）
Abstract:The Hastelloy C22 coatings on Q235 steel substrate were produced by high power diode laser cladding technique. Their corrosion behaviors in static and cavitation hydrochloric, sulfuric and nitric acid solutions were investigated. The electrochemical results show that corrosion resistance of coatings in static acid solutions is higher than that in cavitation ones. In each case, coating corrosion resistance in descending order is in nitric, sulfuric and hydrochloric acid solutions. Obvious erosion-corrosion morphology and serious intercrystalline corrosion of coating are noticed in cavitation hydrochloric acid solution. This is mainly ascribed to the aggressive ions in hydrochloric acid solution and mechanical effect from cavitation bubbles collapse. While coating after corrosion test in cavitation nitric acid solution shows nearly unchanged surface morphology. The results indicate that the associated action of cavitation and property of acid solution determines the corrosion development of coating. Hastelloy C22 coating exhibits better corrosion resistance in oxidizing acid solution for the stable formation of dense oxide film on the surface.
Key words: Hastelloy C22 coating; laser cladding; acid solution; cavitation corrosion; electrochemical impedance spectroscopy
