Abstract:According to the principles of simultaneous equilibrium and mass equilibrium, the thermodynamics model of the precipitation-coordination equilibrium of Ni²⁺-C₂H₈N₂- -H₂O system was established, and calculation for the relationships between concentration of each substance in solution and parameters was carried out, including pH value, concentrations of ethylenediamine and oxalate by MATLAB program. The results show that Ni exists as Ni²⁺ and [Ni(C₂O₄)_n]^2-2n mainly at pH<1 and pH=1-6, respectively. When pH> 6, the complex between Ni²⁺ and ethylenediamine is predominant. The precursor of Ni microfiber was prepared by an oxalate precipitation process using ethylenediamine as a coordination agent, and the role of ethylenediamine in the growth of the precursor fiber was discussed. The Ni microfiber can be obtained by a thermal decomposition-reduction process of the precursor in N₂ and H₂ mixed atmosphere. The diameters and aspect ratios of the obtained Ni microfibers are 0.2-1 μm and 20-30, respectively.

Key words: thermodynamics analysis; Ni microfiber; precursor; thermal decomposition; reduction