Abstract:For the purpose of effective and economic desulfurization of flue-gas, the predominance area diagram of the Mn-S-O system at different temperatures was constructed based on the thermodynamic data obtained from the literatures. It is seen from this figure that flue-gas desulfurization by manganese oxides is feasible from the thermodynamic point of view. Additionally, the most appropriate temperature range for flue-gas desulfurization is between 600 and 800 K, and the reaction is strongly exothermic to maintain the heat balance. The natural manganese ores encompass large tunnels that exhibit large surface areas and highly chemical activity, which can provide a high enough SO₂ removing efficiency. From the superposition of the diagrams of Mn-S-O and Fe-S-O systems, it is found that there is a coexistent stability region of MnSO₄ and Fe₂O₃, which provides the possibility of desulfurization by selective sulfation without ferric sulfate forming. A multi-stage desulfurization system has been discussed briefly.

Key words: predominance area diagram; desulfurization; manganese oxides; dry FGD processes