Abstract:β-Sialon/ZrN/ZrON composites were successfully fabricated by an in-situ carbothermal reduction-nitridation process with fly ash, zircon and active carbon as raw materials. The effects of raw materials composition and holding time on synthesis process were investigated, and the formation process of the composites was also discussed. The phase composition and microstructure of the composites were characterized by means of XRD and SEM. It was found that increasing carbon content in a sample and holding time could promote the formation of β-Sialon, ZrN and ZrON. The proper processing parameters to synthesize β-Sialon/ZrN/ZrON composites were mass ratio of zircon to fly ash to active carbon of 49:100:100, synthesis temperature of 1550 °C and holding time of 15 h. The average grain size of β-Sialon and ZrN(ZrON) synthesized at 1550 °C for 15 h reached about 2 and 1 μm, respectively. The fabrication process of β-Sialon/ZrN/ZrON composites included the formation of β-Sialon and ZrO₂ as well as the conversion of ZrO₂ to ZrN and ZrON.

Key words: Sialon; ZrN; ZrON; in-situ synthesis; carbothermal reduction-nitridation process; fly ash; zircon