(遼寧工程技術(shù)大學(xué) 材料科學(xué)與工程學(xué)院,阜新 123000)
摘 要: 往(Fe-Cr)(40)-Al(60)粉末中加入1%(質(zhì)量分?jǐn)?shù))的鎢精礦粉,利用激光引燃自蔓延燒結(jié)制備原位自生顆粒增強(qiáng)復(fù)合材料。通過SEM、XRD等微觀組織結(jié)構(gòu)表征手段及合金密度、孔隙率、硬度、磨損性能等宏觀力學(xué)性能及腐蝕性能測試的方法,研究不同引燃功率對(duì)燒結(jié)合金組織及性能的影響。結(jié)果表明:燒結(jié)合金物相主要為AlFe、AlFe3、Al2O3、Al65Fe20W15、W及硬質(zhì)顆粒相WO3。燒結(jié)合金組織為針片狀,且隨功率的增加,組織變得均勻細(xì)密。當(dāng)功率達(dá)到1 100 W時(shí),燒結(jié)合金密度最大,為4.47 g/cm3,孔隙率最小,為4.43%;硬度最高,表層區(qū)達(dá)到1 309.7HK,中部區(qū)達(dá)到1 003.1HK;合金耐蝕性能最好,鈍化區(qū)最長為440 mV,鈍化電流密度最小為5.570 μA/mm2。而當(dāng)燒結(jié)功率為1 000 W時(shí),試樣磨損率最低,表層區(qū)為0.06 mg/mm2,中部區(qū)為0.05 mg/mm2。
關(guān)鍵字: Fe-Al金屬間化合物;激光燒結(jié);顯微組織;性能
(College of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, China)
Abstract:By putting 1% (mass fraction) tungsten concentrate powders into(Fe-Cr)(40)-Al(60) powders and using laser ignition induced SHS, the in situ antigenic particle reinforced composite alloy was prepared. By means of SEM, XRD, alloy density, porosity, hardness test, abrasion test and corrosion resistance, the effect of different ignition powers on the sintered alloy microstructure and properties was studied. The results show that the product phases of the sintered alloys are AlFe, AlFe3, Al2O3, Al65Fe20W15, W and WO3. The sintered alloy exhibits batten organization, and with the increase of the laser sintering power, the battens get more homogeneous and even small. When the laser sintering power is up to 1 100 W, the sintered alloy achieves the maximum density of 4.47 g/cm3 and the minimum porosity of 4.43%; the highest hardness of the surface layer is 1 309.7HK, that of the middle layer is 1 003.1HK; the corrosion resistance is the best, the longest passivation area is 440 mV and the passivation current density is only 5.570 μA/mm2. When the laser sintering power gets to 1 000 W, the relative wear rate of the sintering alloy is the lowest, the abrasion rate of the surface layer is 0.06 mg/mm2 and that of the middle layer is 0.05 mg/mm2.
Key words: Fe-Al intermetallic compound; laser sintering; microstructure; property


