(中南大學(xué) 材料科學(xué)與工程學(xué)院，長沙 410083)
摘 要: 鎂陽極材料具有電負(fù)性好，比能量高以及密度小等優(yōu)異性能，在海水電池領(lǐng)域具有廣闊的應(yīng)用前景。綜述了近年來國內(nèi)外鎂陽極海水電池的研究及應(yīng)用，討論鎂陽極材料的活化機(jī)制和腐蝕行為，探討合金元素和第二相對鎂陽極電化學(xué)活性和耐腐蝕性能的影響，指出今后海水電池用鎂陽極材料的發(fā)展應(yīng)在充分研究合金元素活化機(jī)理和第二相影響的基礎(chǔ)上，研制出自腐蝕速率更小、陽極利用率更高以及比能量更大的新型鎂合金陽極材料。
關(guān)鍵字: 海水電池；鎂陽極；活化；腐蝕；合金元素；第二相
magnesium anode materials in seawater battery
（School of Materials Science and Engineering, Central South University, Changsha 410083, China）
Abstract:The magnesium anodes have great development in seawater battery due to their excellent properties, such as good electro negativity, high specific capacity and low density. The researches and applications of magnesium anodes in seawater battery in recent years were reviewed. The influences of activation mechanism, corrosion behavior, alloying elements and second phases on the electrochemical and corrosion properties of magnesium anodes were discussed. It is indicated that the development of magnesium anodes in seawater battery is to prepare novel anode materials with less self-corrosion, higher anode utilization ratio and larger specific energy based on studying activation mechanism of alloying elements and second phases.
Key words: seawater battery; magnesium anode; activation; corrosion; alloying element; second phase
