(中國(guó)科學(xué)院上海冶金研究所，上海200050)
摘 要: 運(yùn)用化學(xué)鍵參數(shù)與模式識(shí)別或人工神經(jīng)網(wǎng)絡(luò)相結(jié)合，研究若干熔鹽相圖中三元化合物的形成規(guī)律和形成判據(jù)。在此基礎(chǔ)上，預(yù)報(bào)若干未知熔鹽相圖，結(jié)果表明CsCI和MnSO4間有1:1化合物，經(jīng)合成、X射線分析和相圖測(cè)量，證實(shí)CsCI ·MnSO4存在。
關(guān)鍵字: 熔鹽相圖 三元化合物 形成規(guī)律 CsCI · MnSO4
（Shanghai Institute of Metallurgy，Chinese Academy of Sciences，Shanghai 200050）
Abstract:By chemical bond parameters and pattern recognition or artificial neural network method，the reg-ularity and criterion of formability of ternary intermediate compounds in some molten salt phase diagrams have been studied. Predicted results indicated that the Cs，Mn|Cl，SO4 system could form anew ternary compound CsCl·MnSO4，which was confirmed by X-ray diffraction and the experimental liquidus measure of a cross section of phase diagram in CsCl-MnSO4 system.
Key words: molten salt phase diagram ternary compounds forming criterion CsCl·MnSO4
