文章編號：(1997)01-49-3
Cu2(ASA)4 配合物的電子光譜
劉偉平1 熊惠周1 楊一昆 1 諶喜珠1 陳植和2 沈志強2 李玲
(1.昆明貴金屬研究所，昆明 650221;
2.昆明醫(yī)學院， 昆明 650031)
摘 要: 采用紫外/可見分光光譜法,結合其他分析技術，研究了 tetrakis-[μ-acetylsalicylato-O1O2]dicopper(Ⅱ)(簡稱Cu2(ASA)4)配合物的電子光譜。實驗結果表明，該配合物有三種類型特征吸收譜帶，分別歸屬為2Eg→2T2gd-d 電子躍遷，Cu→Cu d-d 電子遷移和RCOO→Cu的電荷轉移。
關鍵字: 乙酰水楊酸 銅配合物 電子光譜
ELECTRONIC SPECTRA OF TETRAKIS- [μ-ACETYLSALICYLATO-O1O2] DICOPPER(Ⅱ) COMPLEX
Liu Weiping1, Xiong Huizhou1, Yang Yikun1, Chen Xizhu1 ,Chen Zhihe2, Shen Zhiqiang2, Li Ling2
（1.Kunming Institute of Precious Metals, Kunming 650221
2.Kunming Medical College, Kunming 650031）
Abstract:The spectra of tetrakis-[μ-acetylsalicylato-O1O2] dicopper(Ⅱ) complex were studied by using ultra-visible spectrum , combined with other analytical techniques. The results showed that the complex has three kinds of absorption bands, which are 2Eg→2T2gd-d transition, Cu→Cu d-d shift and RCOO→Cu charge transfer.
Key words: acetylsalicylate copper(Ⅱ) complex electronic spectrum
