Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

您目前所在的位置:首頁 - 期刊簡介 - 詳細頁面

中國有色金屬學(xué)報

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

[PDF全文下載]        

    

文章編號:1004-0609(2008)10-1926-05
多組分稀土串級萃取有效分離系數(shù)的理論分析
鐘學(xué)明

(南昌航空大學(xué) 環(huán)境與化學(xué)工程學(xué)院,南昌 330063)

摘 要:

通過數(shù)學(xué)表達式研究多組分稀土串級萃取有效分離系數(shù)的理論規(guī)則,提出計算有效分離系數(shù)的平均分數(shù)法,對等效組分法、產(chǎn)品分數(shù)法和平均分數(shù)法計算結(jié)果進行理論分析。結(jié)果表明:有效分離系數(shù)存在極值規(guī)則、比例規(guī)則和權(quán)重規(guī)則;只有平均分數(shù)法完全遵循極值規(guī)則、比例規(guī)則和權(quán)重規(guī)則:平均分數(shù)法的計算結(jié)果,介于極大值和極小值之間,而且隨組分摩爾分數(shù)變化的趨勢是合理的:平均分數(shù)法計算的極值誤差為0;與等效組分法和產(chǎn)品分數(shù)法相比,在整個空間分布中平均分數(shù)法的準確度明顯更高。

 

關(guān)鍵字: 多組分;稀土;串級萃取;有效分離系數(shù);理論規(guī)則;平均分數(shù)法

Theoretical analysis of effective separation factor for multi-component rare earths in countercurrent extraction
ZHONG Xue-ming

School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China

Abstract:The theoretical rules for effective separation factor of multi-component rare earths in counter-current extraction were investigated by mathematical expression. The average fraction method to calculate effective separation factor was presented. Theoretical analyses were made to the calculation results by equivalent component method (EC), product fraction method (PF) and average fraction method (AF). The results show that there are Rule Extremum, Rule Proportion and Rule Weight for the factor. Only average fraction method could completely follow these three rules. The calculation results by average fraction method range between the maximum and minimum, and the movement trends of calculation results are in reason along with component mole fractions. The errors of extremums by average fraction method are 0. In the entire space range the average fraction method is much more accurate than the others.

 

Key words: multi-component; rare earth; countercurrent extraction; effective separation factor; theoretical rule; average fraction method

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學(xué)報》編輯部
------------------------------------------------------------------------------------------
地 址:湖南省長沙市岳麓山中南大學(xué)內(nèi) 郵編:410083
電 話:0731-88876765,88877197,88830410   傳真:0731-88877197   電子郵箱:f_ysxb@163.com  
惠州市| 阳城县| 温泉县| 郓城县| 贵南县| 色达县| 陆良县| 兴隆县| 昌邑市| 绵阳市| 汽车| 石狮市| 罗甸县| 临猗县| 始兴县| 铜川市| 金坛市| 郧西县| 玉树县| 谢通门县| 永德县| 南和县| 当涂县| 沅陵县| 普格县| 巫山县| 伊吾县| 堆龙德庆县| 响水县| 泗水县| 茂名市| 舞阳县| 德兴市| 汝阳县| 辉南县| 彰武县| 福清市| 阿勒泰市| 祁门县| 通辽市| 七台河市|