Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

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文章編號:1004-0609(2008)10-1903-06
高鐵一水硬鋁石型鋁土礦的低鈣比燒結(jié)
劉桂華,張 明,肖 偉,彭志宏,周秋生,李小斌

(中南大學 冶金科學與工程學院,長沙 410083)

摘 要:

研究燒結(jié)法處理我國高鐵中等品位礦石的工藝條件,確定鈣比為1.5時熟料中存在3CaO·2SiO2和2CaO·2SiO2。結(jié)果表明,增大鈣比使熟料Al2O3溶出率、SiO2溶出率均有所降低;延長燒成時間,提高燒成溫度有利于Al2O3溶出率的增加和SiO2溶出率的降低;提高鐵鋁比,熟料最佳燒成溫度降低,燒成溫度范圍變窄;提出的Al2O3有效溶出率概念表明,鈣比為1.5時,熟料燒成效果最好;確定高鐵鋁土礦適宜的燒成制度為:燒成溫度1 250~1 300 ℃,燒成時間20~40 min,鈣比1.5。

 

關(guān)鍵字: 高鐵一水硬鋁石;燒結(jié);低鈣比;有效溶出率

Sintering process of diasporic bauxite with high iron content at low ratio of lime to silica for alumina production
LIU Gui-hua, ZHANG Ming, XIAO Wei, PENG Zhi-hong, ZHOU Qiu-sheng, LI Xiao-bin

School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China

Abstract:The sintering process of diasporic bauxite with high iron content was studied. The results show that 3CaO•2SiO2, and 2CaO•SiO2, are primarily formed in the sintering process when diasporic bauxite is sintered at soda ratio Na2O/(Al2O3+Fe2O3) of 1 and lime ratio CaO/SiO2 of 1.5. The increase of n(CaO)/n(SiO2) decreases the extraction of alumina and silica. The prolongation of sintering time and the increase of sintering temperature benefit the alumina extraction but reduce the silica extraction. The increase of the ratio of iron to alumina decreases the sintering temperature and narrows the sintering temperature range. The results from the Al2O3 available extraction rate also indicate that the high alumina extraction rate can be obtained at n(CaO)/n(SiO2) of 1.5. The feasible technology for sintering is as follows: sintering temperature 1 250−1 300 ℃, sintering time 20−40 min, n(CaO)/n(SiO2) of 1.5.

 

Key words: diaspore with high iron; sinter; low molar ratio of CaO to SiO2; available extraction rate

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學技術(shù)協(xié)會 主辦:中國有色金屬學會 承辦:中南大學
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