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中國有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第2期    總第107期    2008年2月

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文章編號:1004-0609(2008)02-0361-05
晶種活化強(qiáng)化鋁酸鈉溶液的種分分解
尹周瀾,曾紀(jì)術(shù),陳啟元

(中南大學(xué) 化學(xué)化工學(xué)院,長沙 410083)

摘 要:

采用一種新方法活化氫氧化鋁晶種,可以強(qiáng)化鋁酸鈉溶液的種分分解。晶種在沸騰的蒸餾水中蒸煮后得到活化,實(shí)驗(yàn)研究了活化晶種對鋁酸鈉溶液種分附聚過程以及全過程的強(qiáng)化分解作用及其對產(chǎn)品粒度分布的影響。在種分附聚實(shí)驗(yàn)中,對于苛堿濃度比較低的鋁酸鈉溶液,晶種活化0.5 h就能有效地提高溶液的分解率,而活化時(shí)間超過0.5 h對分解率的促進(jìn)作用不明顯;對于苛堿濃度比較高的鋁酸鈉溶液,晶種活化2.0 h以上才能較明顯地提高溶液的分解率。在種分全過程實(shí)驗(yàn)中,溶液分解率的提高在10 h以后出現(xiàn)并逐漸增大。晶種被活化可能是因?yàn)榫ХN表面被有機(jī)雜質(zhì)吸附封閉的活性點(diǎn)被活化后重新顯露,活化晶種及原始晶種在溶液中種分1.0 h后的形貌初步證實(shí)了這種設(shè)想。種分附聚產(chǎn)品的粒度分布結(jié)果顯示,只要晶種活化時(shí)間合適,產(chǎn)品的粒度也能明顯改善。

 

關(guān)鍵字: 氫氧化鋁晶種;晶種活化;鋁酸鈉溶液;晶種分解;粒度分布

Decomposition enhancement of seeded sodium aluminate liquor by activated seed
ZENG Ji-shu, YIN Zhou-lan, CHEN Qi-yuan

School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China

Abstract:The aluminium hydroxide seed was activated by boiling distilled water. The effects of activated seed on decomposition ratio of seeded sodium aluminate liquor and particle size distribution were investigated. The experiments were carried out both at the agglomeration stage and the whole process. In the agglomeration stage, the decomposition ratio of sodium aluminate liquor is improved apparently with the addition of the seed activated for 0.5 h at low concentration of caustic alkali, and the effect is decreased when seed is activated for more than 0.5 h. While at higher concentration of caustic alkali, the enhancement is not evident only after the seed is activated more than 2.0 h. In the whole process, the enhancement can be observed after 10 h. It is assumed that the active sites blocked by organic impurities on the surface of original seed reappear after activation and the activity of seed is increased, which is approved by the morphology of Al(OH)3 product taken from liquor. The particle size distribution of product indicates that the size distribution of particles can also be improved if the activation time is proper.

 

Key words: aluminium hydroxide seed; seed activation; sodium aluminate liquor; agglomeration; particle size distribution

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學(xué)報(bào)》編輯部
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