Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第3期    總第108期    2008年3月

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文章編號(hào):1004-0609(2008)03-0383-05
原位生長(zhǎng)碳納米管對(duì)炭/炭復(fù)合材料導(dǎo)熱性能的影響
周建偉,廖寄喬,王占鋒

(中南大學(xué) 粉末冶金國(guó)家重點(diǎn)實(shí)驗(yàn)室,長(zhǎng)沙 410083)

摘 要:

以炭纖維表面原位生長(zhǎng)有碳納米管(Carbon nanotubes, CNTs)的針刺氈體作為前驅(qū)體制備出生長(zhǎng)有CNTs的炭/炭復(fù)合材料,并與在同樣工藝條件下通過(guò)致密化最終熱處理得到的純炭/炭復(fù)合材料進(jìn)行對(duì)比。結(jié)果表明,在密度幾乎相同的情況下,生長(zhǎng)有CNTs的炭/炭復(fù)合材料的室溫Z軸熱導(dǎo)率約為11.10 W/(m·K),幾乎為純炭/炭復(fù)合材料的室溫Z軸熱導(dǎo)率(6.28 W/(m·K))的2倍,其原因可能在于:CNTs可以有效改善炭纖維和熱解炭之間的界面特性,明顯減少炭/炭復(fù)合材料中纖維和熱解炭界面處周裂紋的出現(xiàn),還可以誘導(dǎo)熱解炭形成一種擁有更高導(dǎo)熱率更易石墨化的粗糙結(jié)構(gòu)。

 

關(guān)鍵字: 碳納米管;炭/炭復(fù)合材料;熱導(dǎo)率;熱解炭

Effect of in situ grown carbon nanotube on thermal conductivity of carbon/carbon composites
ZHOU Jian-wei, LIAO Ji-qiao, WANG Zhan-feng

State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract:Carbon nanotubes(CNTs)-grown carbon/carbon (C/C) composites which have CNTs in situ grown on carbon fibers of needled carbon fiber felts, and pure carbon/carbon composites were fabricated by the chemical vapor infiltration (CVI) method to investigate the effect of CNTs on room temperature Z direction thermal conductivity of C/C composites. Thermal conductivity of samples were tested by laser flash method. The results show that the room temperature Z direction thermal conductivity of CNTs-grown C/C composites is about 11.10 W/(m•K) which is generally 2 times that of pure C/C composites with nearly the same density. The reason is that the favorable effect of CNTs on room temperature Z direction thermal conductivity of C/C composites is achieved by better interfacial properties and formation of high-textured pyrocarbon that has better graphitizability and higher thermal conductivity than other types of pyrocarbon.

 

Key words: C/C composites; thermal conductivity; pyrocarbon

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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