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中國有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第6期    總第111期    2008年6月

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文章編號(hào):1004-0609(2008)06-1143-09
嗜酸硫氧化細(xì)菌作用下元素硫化學(xué)形態(tài)的研究進(jìn)展
何 環(huán),夏金蘭,彭安安,張成桂,邱冠周

(中南大學(xué) 資源加工與生物工程學(xué)院 生物冶金教育部重點(diǎn)實(shí)驗(yàn)室,長沙 410083)

摘 要:

嗜酸硫氧化細(xì)菌是生物冶金過程中研究最為廣泛的細(xì)菌,廣泛分布在含硫和硫化物豐富的環(huán)境中。嗜酸硫氧化細(xì)菌作用下,單質(zhì)硫及其它還原型硫化物(包括金屬硫化礦)經(jīng)過一系列形態(tài)轉(zhuǎn)換使得硫在其細(xì)胞體內(nèi)、體外和環(huán)境沉積物中存在著不同形態(tài)分布。單質(zhì)硫經(jīng)細(xì)菌細(xì)胞活化后在細(xì)胞體內(nèi)以硫球形式積累;還原型硫化物可被細(xì)菌氧化至硫酸鹽,其氧化中間態(tài)多為單質(zhì)硫或連多硫酸鹽等。有關(guān)嗜酸硫氧化細(xì)菌作用下硫的形態(tài)研究十分缺乏,進(jìn)一步開展嗜酸硫氧化細(xì)菌作用下元素硫化學(xué)形態(tài)的研究可以為這類細(xì)菌的硫氧化機(jī)制及對硫化礦的浸出機(jī)理的闡明提供理論依據(jù)。

 

關(guān)鍵字: 嗜酸硫氧化細(xì)菌;硫化學(xué)形態(tài);元素硫?qū)樱涣蚯颍涣蛉苣z

Research progress of sulfur chemical speciation impacted by acidophilic sulfur-oxidizing bacteria
HE Huan, XIA Jin-lan, PENG An-an, ZHANG Cheng-gui, QIU Guan-zhou

Key Laboratory of Biometallurgy of Ministry of Education of China, School of Resources Processing and Bioengineering, Central South University, Changsha 410083, China

Abstract:Acidophilic sulfur-oxidizing bacteria (SOB) are the mostly studied bioleaching bacteria which exists widely in the elemental sulfur and sulfides-containing environments. Under impaction by SOB, the solid sulfur and other reduced sulfides (including metal sulfides) are distributed in different chemical speciations inside or outside the cells as well as in the pertinent environmental deposit. The sulfur globules may be stored intra-cellularly after the solid sulfur is activated and transported by the bacteria. The reduced sulfur compounds, with polythiosulfate and/or elemental sulfur as the main transients, are finally oxidized to sulfuric acid. The chemical speciation of elemental sulfur impacted by various SOB was very poorly investigated, further research may provide theoretical support to the elucidation of sulfur metabolism of acidophilic SOB.

 

Key words: acidophilic sulfur-oxidizing bacteria; chemical speciation; elemental sulfur layer; sulfur globule; sulfur colloid

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會(huì) 主辦:中國有色金屬學(xué)會(huì) 承辦:中南大學(xué)
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