Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第7期    總第112期    2008年7月

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文章編號:1004-0609(2008)07-1347-06
超聲場輔助礦漿電解法制備超細(xì)銅粉
劉維平1,邱定蕃2,于月光2

(1. 江蘇技術(shù)師范學(xué)院 化學(xué)化工學(xué)院,常州 213001;
2. 北京礦冶研究總院 有色冶金研究所,北京 100044
)

摘 要:

采用銅精礦為原料,通過機械活化和超聲場的輔助作用,直接在礦漿電解槽中將銅精礦制備成平均粒度小于10 μm的超細(xì)銅粉。分析礦漿電解制備超細(xì)銅粉的基本原理,研究電流密度和超聲波對超細(xì)銅粉粒度和形貌的影響。結(jié)果表明:提高電流密度有利于超細(xì)銅粉的形成,隨著電流密度的增加,銅粉粒度不斷下降,比表面積不斷上升;與未經(jīng)超聲處理相比,采用超聲場輔助礦漿電解法制備得到的銅粉粒度趨于下降,比表面積上升,且隨著超聲時間的延長,粒度下降越多,比表面積增加越大。

 

關(guān)鍵字: 超細(xì)銅粉;超聲場;礦漿電解

Ultrafine copper powder prepared by
slurry electrolysis under ultrasonic field
LIU Wei-ping1, QIU Ding-fan2, YU Yue-guang2

1. School of Chemical Engineering, Jiangsu Teacher’s University of Technology, Changzhou 213001, China;
2. Institute of Nonferrous Metallurgy, Beijing General Research Institute of Mining and Metallurgy,
Beijing 100044, China

Abstract:Using copper concentrate as raw material, ultrafine copper powder by using slurry electrolysis with average size of less than 10 μm was gained in the slurry electrolysis cell under ultrasonic field and mechanical activation pretreatment. The basic principle of using slurry electrolysis to prepare ultrafine copper powder was briefly analyzed, and the influence of current density and ultrasonic on the size and shape of ultrafine copper powder were studied. The results show that high current density is propitious to the forming of ultrafine copper powder, the particle size of copper powder decreases and the specific surface area increases with increasing current density. Compared with the non-ultrasonic process, the size of copper powder produced by slurry electrolysis under ultrasonic field decreases, and the specific surface area increases. The particle size of copper powder decreases more while the specific surface area increases more with prolonging ultrasonic treating time.

 

Key words: ultrafine copper powder; ultrasonic field; slurry electrolysis

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學(xué)報》編輯部
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