Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第7期    總第100期    2007年7月

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文章編號(hào):1004-0609(2007)07-1053-05
AZ31鎂合金表面液相滲鋁的工藝與性能
譚成文1, 2,郭冠偉2,王瀟屹2,王富恥2,才鴻年1, 2

(1. 北京理工大學(xué) 材料科學(xué)與工程學(xué)院, 北京100081;
2. 北京航空航天大學(xué) 材料科學(xué)與工程學(xué)院, 北京100083
)

摘 要:

采用液相擴(kuò)滲技術(shù)在擠壓態(tài)AZ31鎂合金表面快速滲入鋁,在合金表面獲得過(guò)共晶滲層,并對(duì)滲層的成分、相組成、擴(kuò)滲過(guò)程、納米硬度和腐蝕性能進(jìn)行分析。結(jié)果表明:AZ31鎂合金在480 ℃熱擴(kuò)滲鋁過(guò)程中發(fā)生了“熔化—凝固”變化,滲層為典型的過(guò)共晶組織;滲鋁層含有Mg17Al12相和鎂的鋁飽和固溶體,這種滲層具有較高的納米硬度和較好的耐腐蝕性能;通過(guò)提高擴(kuò)滲溫度進(jìn)行液相擴(kuò)滲可以大大提高擴(kuò)滲速度,但由于快速凝固收縮會(huì)造成表層產(chǎn)生起伏現(xiàn)象,控制冷卻速度可以將表層起伏控制在可接受的范圍。

 

關(guān)鍵字: AZ31鎂合金;過(guò)共晶滲層;耐蝕性;納米硬度

Processes and properties of liquid aluminized
coating on AZ31 magnesium alloy
TAN Cheng-wen1, 2, GUO Guan-wei2, WANG Xiao-yi2,
WANG Fu-chi2, CAI Hong-nian1, 2

1. School of Materials Science and Engineering, Beijing Institute of Technology,
Beijing 100081, China;
2. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics,
Beijing 100083,China

Abstract:Liquid diffusion technology was used to aluminize on the surface of AZ31 magnesium alloy. The hypereutectic aluminized coating was obtained. The forming mechanism and properties of aluminized coating were studied by analyzing the component, phase state, nanoindentation hardness and corrosion resistance. The results show that a solidification-melting process occurs on the surface of AZ31 magnesium alloy when it is aluminized at 480 ℃. Mg17Al12 and Mg-Al supersaturated solid solution exist in the aluminized coating, and the coating nanoindentation hardness is about 3 times higher than that of AZ31 magnesium matrix, at the same time the corrosion resistance is improved obviously. Aluminizing in liquid phase may improve the diffusion velocity but up-and-down surface is formed due to surface solidification shrinkage from liquid phase, which can be controlled by reducing the cooling velocity.

 

Key words: AZ31 magnesium alloy; hypereutectic coating; corrosion resistance; nanoindentation hardness

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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