Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第1期    總第94期    2007年1月

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文章編號(hào):1004-0609(2007)01-0131-07
塊體Mg65Cu22Ni3Y10非晶態(tài)合金的
制備及在焊接中的應(yīng)用
陳振華,司乃潮,張扣山,趙 偉

(江蘇大學(xué) 材料科學(xué)與工程學(xué)院, 鎮(zhèn)江 212013)

摘 要:

利用銅模澆鑄法制備了厚度為2 mm、成分為Mg65Cu22Ni3Y10塊體合金試樣,并通過X射線衍射、差熱掃描量熱儀證實(shí)其為完全的非晶態(tài)。以鎂合金AM60B為母材、2 mm厚的Mg65Cu22Ni3Y10板狀非晶態(tài)合金為中間層,在420~540 ℃下進(jìn)行焊接,利用金相顯微鏡、掃描電鏡(SEM)和能譜儀研究了焊接接頭的微觀形貌和成分分布。結(jié)果表明:界面接合良好,未觀察到片狀?yuàn)A雜物、氣孔及未焊合等缺陷;焊縫區(qū)由塊狀α-Mg相和針狀化合物組成,基體中的Al元素通過晶界擴(kuò)散偏聚到焊縫中,微量Y元素?cái)U(kuò)散到基體中,有少量的Mn和Cu元素發(fā)生偏聚,Ni元素分布均勻,沒有發(fā)生偏聚現(xiàn)象。

 

關(guān)鍵字: Mg65Cu22Ni3Y10;非晶態(tài)合金;擴(kuò)散釬焊;相界擴(kuò)散;非晶態(tài)釬料

Preparation and application in welding of bulk
Mg65Cu22Ni3Y10 amorphous alloys
CHEN Zhen-hua, SI Nai-chao, ZHANG Kou-shan, ZHAO Wei

School of Material Science and Engineering, Jiangsu University,Zhenjiang 212013, China

Abstract:Bulk Mg65Cu22Ni3Y10 alloy with thickness of 2 mm was fabricated by casting in a traditional copper mould. Full amorphous structure was confirmed by X-ray diffractometry and differential scanning calorimetry (DSC). A welding experiment was performed using Mg-based alloys AM60B as base metal and bulk Mg65Cu22Ni3Y10 amorphous alloy as interlayer between 420 ℃ and 540 ℃. The microstructures and elements distribution of the brazed joints were analyzed by metallographic microscopy, SEM and EDS. The results show that a sound bonded interface is obtained without sheet inclusion, pore and unbinding. The microstructure consists of bulk α-Mg phase and needle compound in the weld metal, element Al diffuses along the grain boundary of the substrate into the welding line. A little Y diffuses into the base metal. A little Mn and Cu segregate and element Ni distributes homogeneously and no segregation appears in weld area.

 

Key words: Mg65Cu22Ni3Y10; amorphous alloy; diffusion brazing; phase boundary diffusion; amorphous solder alloys

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會(huì) 主辦:中國有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國有色金屬學(xué)報(bào)》編輯部
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