Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第1期    總第94期    2007年1月

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文章編號(hào):1004-0609(2007)01-0035-04
稀磁半導(dǎo)體Zn1−xNixO的室溫鐵磁性
彭 坤1, 2,周靈平1,胡愛(ài)平1,唐元洪1

(1. 湖南大學(xué) 材料科學(xué)與工程學(xué)院,長(zhǎng)沙 410082;
2. 中南大學(xué) 粉末冶金國(guó)家重點(diǎn)實(shí)驗(yàn)室,長(zhǎng)沙 410083
)

摘 要:

利用溶膠-凝膠方法制備不同成分的Zn1−xNixO(x=0.05,0.10,0.15)稀磁半導(dǎo)體材料,產(chǎn)物由直徑約70 nm的六邊形顆粒組成。利用振動(dòng)樣品磁強(qiáng)計(jì)測(cè)量了樣品的磁學(xué)性能,發(fā)現(xiàn)在室溫條件下存在明顯的鐵磁性,且隨著鎳濃度的增加,樣品的飽和磁化強(qiáng)度增加,但樣品的單個(gè)鎳原子的磁矩是逐漸下降的。X射線(xiàn)衍射分析結(jié)果表明,樣品中不存在鎳及鎳的氧化物,且晶格常數(shù)隨鎳含量的增加而略有增大,并利用M—T曲線(xiàn)測(cè)量Zn0.9Ni0.1O居里溫度為575 K左右,表明其磁性來(lái)源于稀磁半導(dǎo)體。

 

關(guān)鍵字: 稀磁半導(dǎo)體;ZnO;鐵磁性

Room temperature ferromagnetism in
Zn1-xNixO diluted magnetic semiconductor
PENG Kun1, 2, ZHOU Ling-ping1, HU Ai-ping1, TANG Yuan-hong1

1. College of Materials Science and Engineering, Hunan University,Changsha 410082, China;
2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract:A series of Zn1-xNixO(x=0.05, 0.10, 0.15) diluted magnetic semiconductors are fabricated by using sol-gel method, and the products consist of hexagonal nanoparticles with about 70 nm in diameter. The measurement of magnetism was carried out by a vibrating samples magnetometer (VSM), it was found that the samples show ferromagnetism under the room temperature, and with the increase of Ni-ion content, the saturated magnetization increase, but the averaged atomic magnetic moments decrease. The X-ray diffraction results show that there is not any pure nickel or nickel-oxide in the samples and the lattice increases with the content of Ni-ion. It was determined that the Curie temperature of Zn0.9Ni0.1O at about 575 K by M—T curves, which confirmed Zn1−xNixO is ferromagnetism under room-temperature.

 

Key words: diluted magnetic semiconductor; ZnO; ferromagnetism

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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