Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 22    No. 10    October 2012

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Microstructures and formation mechanism of headstand pyrocarbon cones developed by electromagnetic-field-assisted CVD
TU Chuan-jun1,2, HUANG Qi-zhong1, ZHANG Ming-yu1, ZHAO Xin-qi2, CHEN Jiang-hua2

1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;
2. College of Materials Science and Engineering, Hunan University, Changsha 410082, China

Abstract:Novel headstand pyrocarbon cones (HPCs) with hollow structure were developed on the surfaces of pyrocarbon layers of the carbon/carbon (C/C) composites at 650-750 °C by the electromagnetic-field-assisted chemical vapor deposition in the absence of catalysts. The fine microstructures of the HPCs were characterized by high-resolution transmission electron microscopy. The results show that the textural features of the HPCs directly transfer from turbostratic structure in roots to a well-ordered high texture in stems. And the degree of high texture ordering decreases gradually from the stem to the tail of the HPCs. The formation mechanism of the HPCs was inferred as the comprehensive effect of polarization induction on electromagnetic fields and particle-filler property under disruptive discharge.

 

Key words: headstand pyrocarbon cones; chemical vapor deposition; electromagnetic-field-assisted method; fine microstructure; formation mechanism

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學技術協(xié)會 主辦:中國有色金屬學會 承辦:中南大學
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