中國(guó)有色金屬學(xué)報(bào)(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 22 No. 10 October 2012 |
（1. School of Mechanical Engineering, Southeast University, Nanjing 210018, China;
2. College of Mechanical and Electrical Engineering,
Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China）
Abstract:Al2O3-13%TiO2 (mass fraction) coatings, prepared by laser cladding on nickel-based alloy, were heated using high frequency induction sources. The coating microstructure and the interface between bond coating and ceramic coating were characterized by SEM, XRD and EDS. The results show that two-layer substructure exists in the ceramic coating: one layer evolving from fully melted region where the sintered grains grow fully; another layer resembling the liquid-phase-sintered structure consisting of three-dimensional net where the melted Al2O3 particles are embedded in the TiO2-rich matrix. The mechanism of the two-layer substructure formation is also explained in terms of the melting and flattening behavior of the powders during laser cladding processing. The spinel compounds NiAl2O4 and acicular compounds Cr2O3 are discovered in the interface between bond coating and ceramic coating. It proves that the chemical reactions in the laser cladding process will significantly enhance the coating adhesion.
Key words: ceramic coating; nickel alloy; laser cladding; Al2O3-TiO2; high frequency induction
