中國有色金屬學(xué)報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 21 No. 10 October 2011 |
（School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China）
Abstract:The leaching kinetics of bastnaesite concentrate in HCl solution was investigated with respect to the effects of HCl concentration by changing HCl concentration, leaching temperature, liquid to solid ratio, and particle size. A particle size of 25 μm was required to leach 89.6% RE2(CO3)3 and 1.5%REF3 at 90 °C for 90 min, when HCl concentration was 6 mol/L and liquid to solid ratio was 15:1. The leaching kinetics of bastnaesite concentrate is represented by shrinking core model with diffusion through a porous product layer. The activation energies for the dissolution reaction of RE2(CO3)3 and REF3 were calculated to be 59.39 kJ/mol and 66.13 kJ/mol respectively.
Key words: bastnaesite; RE2(CO3)3; REF3; leaching kinetics
