Abstract:In order to improve the hydrogen storage kinetics of the Mg₂Ni-type alloys, Ni in the alloy was partially substituted with element Co. The Mg₂Ni-type Mg₂Ni_1−xCo_x (x=0, 0.1, 0.2, 0.3, 0.4) alloys were fabricated by melt-spinning technique. The structures of the as-spun alloys were characterized by XRD and TEM. The gaseous and electrochemical hydrogen storage kinetics of the alloys was measured. The results show that the substitution of Co for Ni notably enhances the glass forming ability of the Mg₂Ni-type alloy. The amorphization degree of the alloys visibly increases with rising of Co content. Furthermore, the substitution of Co for Ni significantly improves the hydrogen storage kinetics of the alloys. With an increase in the amount of Co substitution from 0 to 0.4, the hydrogen absorption saturation ratio of the as-spun (15 m/s) alloy increases from 81.2% to 84.9%, the hydrogen desorption ratio from 17.60% to 64.79%, the hydrogen diffusion coefficient increases from 1.07×10⁻¹¹ to 2.79×10^{−11 cm2}/s and the limiting current density increases from 46.7 to 191.7 mA/g, respectively.

Key words: Mg₂Ni-type alloy; substituting Ni with Co; melt spinning; hydrogen storage kinetics