中國有色金屬學(xué)報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 21 No. 1 January 2011 |
direct methanol fuel cell by citrate-stabilized method
DU Ke1, HU Guo-rong1, LIU Ye-xiang1
（1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;
2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China）
Abstract:Platinum nanoparticles supported on carbons (Pt/C, 60%, mass fraction) electrocatalysts for direct methanol fuel cell (DMFC) were prepared by citrate-stabilized method with different reductants and carbon supports. The catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and cyclic voltammetry (CV). It is found that the size of Pt nanoparticles on carbon is controllable by citrate addition and reductant optimization, and the form of carbon support has a great influence on electrocatalytic activity of catalysts. The citrate-stabilized Pt nanoparticles supported on BP2000 carbon, which was reduced by formaldehyde, exhibit the best performance with about 2 nm in diameter and 66.46 m2/g (Pt) in electrocatalytic active surface (EAS) area. Test on single DMFC with 60% (mass fraction) Pt/BP2000 as cathode electrocatalyst showed maximum power density at 78.8 mW/cm2.
Key words: direct methanol fuel cell; catalyst; Pt/C; citrate; reductant; carbon support
