中國有色金屬學(xué)報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 9 No. 1 March 1999 |
State Key Laboratoryfor Powder Metallurgy,
（Central South University of Technology, Changsha 410083, P. R. China）
Abstract:Gels of Zr(OH)4and Y(OH)3, prepared by the chemical coprecipitation method, were effectively dehydrated by the azeotropic distillation processing. Because of the removal of interparticle free water, replacement of surface hydroxyl groups with butoxy groups and steric effects of n-butanol, colse approach of gel particles and Zr-O-Zr chemical bond formation between them were prevented. Nanometer ZrO2-8%(mole fraction, %)Y2O3powders prepared by this processing, with the average particle size of 16 nm, can be sintered to 98.5% TD at 1 450℃for 2 h with an average grain size of ceramic of 0.3μm.
Key words: ZrO2-8%Y2O3 nanometer powder chemical coprecipitation method azeotropic distillation hard agglomerate
