Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報(bào)(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    Special 1    May 2010

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Behavior of arsenic in zinc electrowinning
YU Xiao-hua(俞小花)1, XIE Gang(謝 剛)1, LI Rong-xing(李榮興)1, LI Yong-gang(李永剛)2, LU Ying(陸 瑩)1

1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology,
Kunming 650093, China;
2. Technology Center of Yunnan Metallurgy Group Co., Kunming 650031, China

Abstract:The effects of arsenic on the cathode polarization process in zinc electrowinning, its kinetics equation, parameters and polarization mechanism were studied by multiple electrochemistry approaches. The experimental results show that, if [As3+]≥3 mg/L, electrowinning first enters into stationary passivation range, and then enters into precipitation range, which indicates that the depolarization function of impurity arsenic is zinc electrowinning.

 

Key words: zinc electrowinning; arsenic; cathode polarization; kinetics equation; parameters

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會(huì) 主辦:中國有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國有色金屬學(xué)報(bào)》編輯部
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