中國(guó)有色金屬學(xué)報(bào)(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 15 No. 4 August 2005 |
Activity coefficient calculation model for
NaAl(OH)4-NaOH-H2O system
NaAl(OH)4-NaOH-H2O system
LI Xiao-bin(李小斌), LÜ Wei-jun(呂衛(wèi)君), LIU Gui-hua(劉桂華),
PENG Zhi-hong(彭志宏), ZHOU Qiu-sheng(周秋生),
MENG Yun(孟 蕓), REN Wan-neng(任萬(wàn)能)
PENG Zhi-hong(彭志宏), ZHOU Qiu-sheng(周秋生),
MENG Yun(孟 蕓), REN Wan-neng(任萬(wàn)能)
（School of Metallurgical Science and Engineering, Central South University,
Changsha 410083, China）
Abstract: Resorting to Debye-Hückel equation, the conception of the apparent dielectric constant ε′ of sodium aluminate solution is introduced. By supposing that all the influences are attributed to it, ε′ is successfully related to caustic ratio αK, concentration mNaOH, T and temperature T. Then an activity coefficient calculation model for NaAl(OH)4-NaOH-H2O system from 25℃ to 100℃ is established, which can be used in much wider αK and mNaOH, T ranges than those covered by the equilibrium solubility data.
Key words: Debye-Hückel equation; activity coefficient; calculation model
