中國有色金屬學(xué)報(bào)(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 14 No. 2 April 2004 |
electrochemical performance of calcium-containing active
material of secondary zinc electrodes①
ZHANG Jian-qing(張鑒清)1,2, CAO Chu-nan(曹楚南)1,2
（1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China;
2. State Key Laboratory for Metals Corrosion and Protection, Shenyang 110015, China）
Abstract:The calcium-containing active material of secondary alkaline zinc electrodes was prepared by a chemical coprecipitation method and characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD). Their electrochemical performance was tested by the Galvanstatic charge-discharge method. The experimental results show that the sample synthesized at pH=11.15 has a typical calcium zincate crystal. The zinc electrode using this sample as active material shows higher discharge capacity, more negative discharge plateau potential and longer cycle lifetime.
Key words: calcium zincate; zinc oxide; zinc electrode; electrochemical performance
