Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報(bào)(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 18    No. 4    August 2008

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Thermal stability and oil absorption of aluminum hydroxide treated by dry modification with different modifiers
ZHOU Xiang-yang(周向陽)1, LI Chang-lin(李昌林)1, HUO Deng-wei(霍登偉)1, 2,
LI Jie(李 劼)1, WU Shang-yuan(伍上元)1

1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;
2. Shandong Branch, China Aluminum Corporation, Zibo 255052, China

Abstract:The thermal stability, particle size and morphology and oil absorption of aluminum hydroxide(ATH) treated by dry modification with three different modifiers were investigated. The experimental results show that the thermal stability of ATH powder is markedly improved by dry modification technology with the following modifiers such as phosphoric acid, polyacrylic acid and the mixture of phosphoric acid and polyacrylic acid. The best effect comes from pure phosphoric acid, and the initial temperature for the loss of crystal water of ATH powder modified with pure polyacrylic acid can reach about 202 ℃ that is approximately 10 ℃ higher than that of ATH powder before modification. The phenomena of agglomeration and macro-aggregate badly exist in ATH powder modified with the modifiers containing phosphoric acid. The growth of particles and agglomerations of powders are not evident in ATH powder modified with pure polyacrylic acid. The oil absorption of ATH powder modified with the modifiers containing phosphoric acid is apparently larger than that of original ATH powder and ATH powder modified with pure polyacrylic acid. The oil absorption of the ATH powder modified with pure polyacrylic acid is slightly smaller than that of original ATH powder.

 

Key words: aluminum hydroxide; dry modification; polyacrylic acid; thermal stability; oil absorption

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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