中國有色金屬學報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 16 No. 3 June 2006 |
（1. Beijing Key Laboratory for Corrosion, Erosion and Surface Technology, University of Science and Technology Beijing, Beijing 100083, China;
2. Faculty of Mechanical and Electrical Engineering, Kunming University of Science and Technology, Kunming 650093, China;
3. Department of Chemical and Materials Engineering, University of Auckland, Private Bag 92019, Auckland）
Abstract:A method was presented to prepare aluminide coatings on metals by combining the pack aluminizing with the ball impact process. This technique applied mechanical vibration to a retort, which was loaded with pack-aluminizing powder, specimens and alloy balls. Pack aluminizing was carried out with repeated ball impact, which accelerated chemical reactions and atomic diffusion. Aluminide coatings were formed at a relatively lower temperature (below 600 ℃) and in a shorter treatment time, compared with the conventional pack aluminizing. The effects of the operation temperature and the treatment time on the formation of the coatings were analysed. The SEM, EDS and XRD analysis results show that the aluminide coatings appear to be homogeneous, with a high density and free of porosity, and have excellent adherence to the substrate. The coatings mainly consist of Al-rich phases such as η-Fe2Al5, θ-FeAl3 and CrAl5. Oxidation resistance was studied by high-temperature tests. The formation mechanism of the Al-coatings was also investigated. This technique provides a new approach for industrial diffusion coatings with great energy and time savings.
Key words: low-temperature pack aluminizing; aluminide coating; ball impact; oxidation resistance
