中國有色金屬學(xué)報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 17 No. 4 August 2007 |
Xiong Chun-hua(熊春華)3, LI Tao(李 濤)2
（1. Department of Chemistry, Lishui University, Lishui 323000, China;
2. Xi’an Power Resin Factory, Xi’an 710038, China;
3. Department of Applied Chemistry, Biotechnology and Environmental Engineering,
Zhejiang Gongshang University, Hangzhou 310035, China）
Abstract:The adsorption properties of XSD-296 for Cr(Ⅵ) were studied by using chemical analysis and infrared spectrometry. Experimental results show that XSD-296 resin has a good adsorption ability for Cr(Ⅵ) at pH=2.6 in the HAc-NaAc medium. The statically saturated adsorption capacity is 235 mg/g resin. The apparent activation energy of adsorption reaction, Ea, is 16.73 kJ/mol, and the thermodynamic parameters are ∆H=11.62 kJ/mol, ∆G298 K=−4.13 kJ/mol. The adsorption behavior of resin for Cr(Ⅵ) is in accordance with Freundlich adsorption isotherm. Cr(Ⅵ) adsorbed on resin can be eluted by 5%NaCl-5%NaOH or 5%NH4Cl-5%NH3∙H2O quantitatively. Infrared spectra and adsorption mechanism show that the functional group of resin coordinates with Cr(Ⅵ) to form co-ordination compound. The coordination molar ratio of the functional group of resin to Cr(Ⅵ) is 1׃1.
Key words: XSD-296 resin; chromium(Ⅵ); adsorption
