中國(guó)有色金屬學(xué)報(bào)(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 17 No. 1 January 2007 |
ZHANG Zhao(張 昭)1, ZHANG Jian-qing(張鑒清)1, 2, CAO Chu-nan(曹楚南)1,2
（1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China;
2. State Key Laboratory for Corrosion and Protection, Metal Research Institute,
The Chinese Academy of Science, Shenyang 110015, China）
Abstract: The point of zero charge(PZC) of SiC nanoparticles was determined by means of standard potentiometric titration method, while the influences of the main technological parameters on the microstructure of electrodeposited Ni-SiC composite film were studied and optimized. The results show that high bath pH value favors SiC nanoparticles negatively charged and high bath temperature promotes them positively charged. Under the experimental conditions, sodium dodecyl-glycol is proven to be an effective surface modification anionic surfactant for SiC nanoparticles. The results also show that the optimized Ni-SiC composite film is composed of the nanoparticles with the average grain size in the nanometer range (100 nm), and SiC nanoparticles disperse into the nickel matrix uniformly.
Key words: Ni-SiC nanocomposite film; point of zero charge; potentiometric titration; electroplating
