Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 33    No. 11    November 2023

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Influence of pH on corrosion resistance of slippery liquid-infused porous surface on magnesium alloy
Wen-hui YAO1,2, Guo-xiang ZHAN1, Yong-hua CHEN1, Jie QIN1, Liang WU1,2, Yan-ning CHEN1, Jia-hao WU1, Bin JIANG1,2, Andrej ATRENS3, Fu-sheng PAN1,2

1. College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China;
2. National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing 400044, China;
3. School of Mechanical and Mining Engineering, The University of Queensland, Brisbane Qld 4072, Australia

Abstract:A slippery liquid-infused porous surface (SLIPS) was developed on the AZ31 Mg alloy to provide corrosion protection. A layered double hydroxide (LDH) was applied to providing accommodation for liquid lubricants. The electrolyte pH was adjusted to obtain the best LDH film for the development of a SLIPS. The surface morphology, surface wettability, and electrochemical behavior of the SLIPS formed at different pH values were investigated. The results indicated that the MgAl-LDH film synthesized at a pH of 10.5 had a maximum thickness of 3.51 μm to accommodate the most silicone oil, with a mass of 0.22 mg/mm2, which provided the best corrosion protection, with the lowest corrosion current density of 3.72×10-9 A/cm2. On the other hand, compared with the superhydrophobic surface, the SLIPS imparted better corrosion resistance for the AZ31 substrate in both electrochemical behavior and long-term immersion test. The improved corrosion resistance of the SLIPS can further accelerate the application of Mg alloys in practice.

 

Key words: slippery liquid-infused porous surface; electrolyte pH; corrosion resistance; surface hydrophobicity; AZ31 Mg alloy

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學(xué)報》編輯部
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