Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 33    No. 9    September 2023

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Strengthening and thermal conductivity behaviors of cast Cu-La-Zn alloys
Bo HU1, Jia-xuan HAN1, De-jiang LI1,2, Ming-di YU1, Jing-ya WANG1, Xue-yang WANG1, Zi-xin LI1, Yu HUANG3, Xiao-qin ZENG1,2

1. National Engineering Research Center of Light Alloy Net Forming, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
2. State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China;
3. Huawei Technologies Co., Ltd., Shenzhen 518129, China

Abstract:A new Cu-La-Zn alloy system with high thermal conductivity was developed for die casting, and the thermal conductivity of this alloy system was 200-300 W/(m·K), which was twice as that of ordinary brass. The effects of Cu6La intermetallic compounds and Zn solute atoms on the strengthening and thermal conductivity behaviors were quantitatively studied in as-cast binary Cu-La (2.0-4.5 wt.% La) and ternary Cu-2La-xZn (0-3.0 wt.% Zn) alloys, respectively. The results showed that for the increase of per 1 wt.% La or Zn, the thermal conductivity decreased by about 34 W/(m·K). In Cu-2La-xZn alloys, the lattice constant of α-Cu matrix increased from 3.6163 to 3.6239 ?. Due to the solid solution strengthening of Zn atoms, the hardness of the α-Cu matrix showed a parabolically increasing tendency, from 1.495 to 1.597 GPa. According to the calculations of the Maxwell-Eucken model based on the microstructure, the thermal conductivity of Cu6La phase was determined to be about 35.37 W/(m·K), and the reduction in thermal conductivity of α-Cu matrix caused by Zn solute atoms was quantified to be 51.38 W/(m·K) per 1.0 at.% Zn increase.

 

Key words: Cu-La-Zn alloy; strengthening; thermal conductivity; intermetallic compound; solute atom

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學技術協(xié)會 主辦:中國有色金屬學會 承辦:中南大學
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